Cross-Condensation Reactions in an Organically Modified Silica Sol-Gel
نویسندگان
چکیده
منابع مشابه
Protein adsorption onto organically modified silica glass leads to a different structure than sol-gel encapsulation.
The secondary structures of two proteins were examined by circular dichroism spectroscopy after adsorption onto a series of organically modified silica glasses. The glasses were prepared by the sol-gel technique and were varied in hydrophobicity by incorporation of 5% methyl, propyl, trifluoropropyl, or n-hexyl silane. Both cytochrome c and apomyoglobin were found to lose secondary structure af...
متن کاملElectrochemical redox reactions in solvated silica sol–gel glass*
The studies of the electrochemical redox reactions in solvated silica sol–gel glass were reviewed. The methodology of the experiments with emphasis on the direct preparation of the solid electrolyte and the application ultramicroelectrodes was described. Generally, the level of the electrochemical signal is not much below that observed in liquid electrolyte. The current depends on time elapsed ...
متن کاملIdentification of self- and cross-condensation products in organically modified silica sols by 29Si and 170 NMR
High resolution 295i and 170 NMR spectroscopy has been used to identify selfand cross-condensation products in sols prepared from tetraethoxysilane (TEOS) and organically modified triethoxysilanes (RTES, where R is a methyl, ethyl or phenyl group). The sols were prepared by the acid catalyzed hydrolysis of TEOS and RTES with H20/Si mole ratios of 0.15, 0.3 or 0.5. Resonance assignments were mad...
متن کاملCarbon–silica sol-gel derived nanomaterials
The preparation of sol-gel derived silica-based nanomaterials containing electrical conductive carbon fillers in an extensive composition range is described and their electrical properties are presented. Nanomaterials of carbon filler concentrations up to 60% (v/v) were obtained by dip coating or screen-printing from precursors of hydrolysed alkoxysilanes. Nanostructured morphology could be ide...
متن کاملSol-gel silica laser tunable in the blue.
Doped and undoped silica slabs were fabricated through the use of the sol-gel technique. Extended UV transmission was observed for HCl-catalyzed sol-gel silica. Under transverse pumping with a XeCl laser, narrow-linewidth (<0.9-nm) laser oscillation from silica slabs doped with coumarin 460 (C460) was achieved in a grating-resonator cavity configured in the grazing-indicence geometry. Tuning of...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: MRS Proceedings
سال: 1994
ISSN: 0272-9172,1946-4274
DOI: 10.1557/proc-346-979